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Corel Paint Shop Pro X3.0 Download – Would you like to download the latest version of Corel Paint Shop Pro X3.0 software which gives you all in one photo editing software like image editing, image optimization, photo manipulation, image retouching, image..This invention relates to a process for the production of polyether polyols by the free radical polymerization of a cyclic ether, such as propylene oxide, which polymerizer contains at least one compound as catalyst, stabilizer and/or monofunctional initiator.
It is known to free radical polymerize cyclic ethers by free-radical polymerization, i.e., polymerization without addition of a C-C double bond, by subjecting the cyclic ether to thermal decomposition, to catalysts which can be used as initiators in this connection, and to a mixture of the catalyst and the initiator or monofunctional initiator. The polymerization can be carried out in the liquid phase or in the gas phase. The temperature required for this process is as a rule in the range from 350.degree. to 500.degree. C., more generally 350.degree. to 450.degree. C. and most generally, again, from 350.degree. to 450.degree. C.
At low temperatures a low exothermicity of the reaction results, while a high exothermicity of the reaction results at high temperatures. The reaction temperature is thus dependent on the equipment used for the reaction. The lower limit of the reaction temperature is governed by the mechanical properties of the equipment, in particular, by stability. The polymerization process can be carried out in tube reactors or in reactors filled with extrusion pelletizers, for example, because the necessary heat transfer can be effected sufficiently there without the need for cooling.
There is also a liquid phase process for the production of polyether polyols by free radical polymerization of cyclic ethers. In a number of cases the thermal decomposition of propylene oxide in homogeneous solution is accompanied by a violent explosion. This requires special safety precautions and risks damage to the plants.
It is also known to free radical polymerize cyclic ethers in the gas phase, whereupon the reaction is carried out at a temperature as a rule in the range from 350.degree. to 450.degree. C. Here, too, the safety aspects in regard to the equipment and the use of explosive starting materials are also great.
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